Elements - Radon
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RADON - KEY INFORMATION
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222Rn  table

Name: radon
Symbol: Rn
Named after "the element radium" (radon was called niton at first, from the Latin word "nitens" meaning "shining")
Block in periodic table: p-block
Standard state: gas
Colour: colourless
CAS: 10043-92-2

Description

At ordinary temperatures radon is a colourless gas. When cooled below the freezing point, radon exhibits a brilliant phosphorescence which becomes yellow as the temperature is lowered and orange-red at the temperature of liquid air.

The main hazard is from inhalation of the element and its decay products which are collected on dust in the air. Recently, radon buildup in homes from the surrounding soil and rocks has become a safety issue and some areas around the world test homes for radon gas. It is the heaviest known gas. Radon is present in some spring waters.
Historical

Radon was discovered in 1900 by Friedrich Ernst Dorn, who called it niton. It is essentially inert. It was called niton but has been called radon since 1923.
Discoveror: Friedrich Ernst Dorn
Discovered at: Germany
Discovery date: 1900

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Atomic number:
86
Standard atomic weight:
222.02
Symbol:
Rn
Group number:
18
Electronic configuration:
[Xe].4f14.5d10.6s2.6p6


Physical state

Standard state: gas
Colour: colourless
Density/kg m-3: n.a. [solid]; 4400 [liquid at boiling point]; 9.73 [gas, 273 K]
Molar volume/cm3: 50.5 [211 K]


Radii /pm

Uncharged
Atomic: n.a.
Covalent: n.a.
van der Waals: n.a.
Metallic: n.a.
Pauling: n.a.
univalent ionic: n.a.

Valence shell orbital radius maxima (Rmax)

orbital : pm
s: 99.7
p: 113.2
d: 49.2
f: 16.8

atomic units
s: 1.88420
p: 2.13933
d: 0.930166
f: 0.317813

Electronegativities

All values are quoted on the Pauling scale apart from absolute values which are given in eV.

Pauling: n.a.
Sanderson: n.a.
Allred Rochow: 2.06
Absolute (/eV): 5.1

Effective nuclear charges

Slater: 8.25
Clementi: 16.08
Froese-Fischer: 20.84

Temperatures /K

melting point: 202
boiling point: 211.4
m.p. hydride: n.a.
b.p. hydride: n.a.
b.p. fluoride: n.a.

Enthalpies /kJ mol-1

fusion: 2.7 (est.)
vaporisation: 18.1

Single bond enthalpies

Rn-F: n.a.
Rn-F: n.a.
Rn-Br: n.a.
Rn-I: n.a.
Rn-Rn: n.a.

Ionization enthalpies

1st: 1037
2nd: 1930
3rd: 2890
4th: 4250
5th: 5310

Isotope data for naturally occurring isotopes

% natural abundance: nil

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